Cottonseed [German version]

Table of contents

General:
Product information
Packaging
Transport
  Container transport
  Cargo securing


Risk factors and loss prevention:
Temperature Odor
Humidity/Moisture Contamination
Ventilation Mechanical influences
Biotic activity Toxicity / Hazards to health
Gases Shrinkage/Shortage
Self-heating / Spontaneous combustion Insect infestation / Diseases




Product information

Product name

German Baumwollsaat
English Cottonseed
French Graine de coton
Spanish Simiente de algodón
Scientific Gossypium spec.
CN/HS number * 1207 20 ff.


(* EU Combined Nomenclature/Harmonized System)



Product description

Cottonseed is the oil-bearing seed of the cotton plant. It belongs to the mallow (Malvaceae) family.

A distinction is drawn between white and black cottonseed, as they differ, particularly in their tendency to self-heating. While with black seed the risk may be classified as slight, with white seed the risk is distinctly greater, owing to its sorption behavior, i.e. its water vapor absorption capacity. The different sorption behavior is caused by cotton fibers, which cling to the white seeds but not to the black ones.

Oil content: 18.0 - 26.0% [1]


Quality / Duration of storage

Cottonseed should be shipped shortly after harvest. To avoid transporting excessively old goods, the year of harvest must be ascertained before loading is begun.


Intended use

Cottonseed is used for oil extraction and as seed.


Figure

(Click on the Figure to enlarge it.)

Photo, seed capsule

Figure 1



Countries of origin

This Table shows only a selection of the most important countries of origin and should not be thought of as exhaustive.

Europe  
Africa Egypt, Angola, Kenya, Sudan
Asia India
America Brazil, Peru, El Salvador
Australia  


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Packaging

Cottonseed is transported as bulk cargo or as break-bulk cargo in bags of woven natural materials (e.g. jute) or woven plastic bags.

Marking of packages
Mark07.gif (2224 bytes)

Keep dry
Mark02.gif (2816 bytes)

Use no hooks
Mark04.gif (3269 bytes)

Keep away
from heat
(solar radiation)


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Transport

Symbols

Symbol, general cargo

General cargo


Bulk cargo



Means of transport

Ship, truck, railroad


Container transport

Ventilated containers (coffee containers), if the lower limits set for the water content of goods, packaging and container flooring and the oil content of the goods are complied with.


Cargo handling

In damp weather (rain, snow), the cargo must be protected from moisture, since it may lead to mold, spoilage and self-heating as a result of increased respiratory activity. 

Hooks must not be used in handling bagged goods as they subject the cargo to point loads, so damaging the bags. Due to their shape, plate or bag hooks apply an area load and are thus more suitable for handling bags.


Stowage factor

1.90 m³/t (jute fabric bags, 55 kg) [1]
2.23 - 2.51 m³/t (bags) [11]



Stowage space requirements

Cool, dry, good ventilation


Segregation

Fiber rope, thin fiber nets


Cargo securing

Bagged cargo must be stowed and secured in the means of transport in such a manner that it cannot slip or shift during transport. If loss of volume and degradation of quality are to be avoided, the packages must not be damaged by other articles or items of cargo.

In the case of maritime transport of bulk cargo, the IMO (International Maritime Organization) "Code of Safe Practice for Solid Bulk Cargoes" must be complied with.


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Risk factors and loss prevention

RF Temperature

Cottonseed requires particular temperature, humidity/moisture and ventilation conditions (SC VII) (storage climate conditions).

Favorable travel temperature range: 5 - 25°C [1]

Temperatures > 30°C should not prevail for an extended period, as such temperatures promote respiration of the cargo and may cause self-heating. The cargo should be stowed away from sources of heat.


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RF Humidity/Moisture

Cottonseed requires particular temperature, humidity/moisture and ventilation conditions (SC VII) (storage climate conditions).

Designation Humidity/water content Source
Relative humidity 70% [1]
Water content 10% [1]
Maximum equilibrium moisture content 65% [1]


Cottonseed must be protected from all forms of moisture (seawater, rain and condensation water), since moisture promotes hydrolytic/enzymatic fat cleavage, which then results in self-heating due to increased respiration. 

The sorption isotherm shows that, at a water content of only 10%, an equilibrium moisture content of 75%, i.e. the mold growth threshold, is reached.

Sorption isotherm

Figure 2



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RF Ventilation

Cottonseed requires particular temperature, humidity/moisture and ventilation conditions (SC VII) (storage climate conditions).

Recommended ventilation conditions: air exchange rate at least 10 changes/hour (airing)

It is advisable to stow so as to leave trenches, so that, where necessary, water vapor and heat may be removed by suitable ventilation measures.


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RF Biotic activity

Cottonseed displays 2nd order biotic activity.

It is a living organ in which respiration processes predominate, because its supply of new nutrients has been cut off by separation from the parent plant.

The fat decomposition which takes place during the course of hydrolytic/enzymatic fat cleavage increases the risk of the cargo undergoing self-heating, possibly ultimately resulting in a cargo fire.


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RF Gases

In cottonseed, metabolic processes continue even after harvesting. The cotton seeds absorb oxygen and excrete carbon dioxide (CO2).

Respiration may cause life-threatening CO2 concentrations (TLV: 0.49 vol.%) or O2 shortages in the hold/container. Therefore, before anybody enters the hold, it must be ventilated and a gas measurement carried out.


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RF Self-heating / Spontaneous combustion

Oil content: 18.0 - 26.0% [1]

The oil content of cottonseed encourages the tendency to self-heating, especially if cotton fibers are still attached to the seeds or the cargo was accepted in damp weather.

Because of its tendency to self-heating/spontaneous combustion, cottonseed may behave like a substance from Class 4.2 of the IMDG Code. See also IMO Code of Safe Practice for Solid Bulk Cargoes.

Fat decomposition in cottonseed leads to the risk of self-heating and, finally, to a cargo fire.

Fat decomposition may proceed as follows:

by hydrolytic/enzymatic fat cleavage or
by oxidative fat cleavage


Hydrolytic/enzymatic fat cleavage:

If the critical water content (10.0%) of cottonseed is exceeded, this promotes hydrolytic/enzymatic fat cleavage. Fat-cleaving enzymes are activated by the elevated water content. The additional action of light and heat may accelerate this process. Free fatty acids sometimes have an unpleasant odor and taste. In the event of extended storage or improper cargo care, these cause the cargo to become rancid.

The free fatty acids formed are consumed by respiration processes in the cottonseed to form carbon dioxide and water, a process which is associated with considerable evolution of heat.

Self-heating of cottonseed is an extremely vigorous process, as the consumption of fatty acids by respiration processes is associated with a considerably greater evolution of heat than is the case with the respiration equation for carbohydrates. Here too, as with cereals, the spoilage process proceeds in a type of chain reaction, because heat and water are formed by the fatty acids consumed by respiration, which in turn contribute to an intensification of the process.

The self-heating of cottonseed requires only a small seat of moisture, so that within just a few hours heating may occur at moist points for which weeks or months would be required in goods dry on shipment.

Fresh cottonseed with a high moisture content tends in particular towards rapid self-heating and may also ignite. Self-heating of cottonseed leads not only to a reduction in the utility value of this product (rancid odor and taste) but also has a qualitative and quantitative effect on oil yield. Self-heating of cottonseed may reduce the yield from oil mills from 43 to 21%. The color and bleachability of the oils are also negatively affected. The oil obtained complicates refining of the crude oils in subsequent processing, because a higher free fatty acid content makes decolorization substantially more difficult.

Hydrolytic/enzymatic fat cleavage and respiration may be limited by low temperatures; however, this may only be affected to a limited degree during transport. It is therefore important to ensure storage stability by complying with the limit values for the water content of the goods.


Oxidative fat cleavage:

Food components frequently react with atmospheric oxygen in spoilage reactions. Atmospheric oxygen may enter into an addition reaction with unsaturated fatty acids through the simultaneous assistance of light, heat and certain fat companion substances, and possibly also traces of heavy metals. It is therefore absolutely essential to store cottonseed in the dark and to protect it from oxygen and metal parts, since otherwise it becomes brown-colored and develops a rancid odor and taste.

Extended storage may affect the oil content, due an increase in the content of free fatty acids.


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RF Odor

Active behavior Cottonseed has a very slight, pleasant odor.
Passive behavior Cottonseed is sensitive to strong foreign odors.



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RF Contamination

Active behavior The high oil content of the goods frequently causes dark fat stains to appear on the bags, which must therefore be kept from coming into contact with goods sensitive to contamination, such as baled goods, tea chests, marble etc..

Cottonseed in bags must not be stowed together with fibers or fibrous materials, either, since oil-impregnated fibers accelerate self-heating processes.

There is also a risk of contamination of other goods by dust formation.
Passive behavior Cottonseed is sensitive to dirt, fats and oils. The holds or containers must accordingly be clean and in a thoroughly hygienic condition before loading.



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RF Mechanical influences

Point loads applied for example by hooks may result in damage (tears) to the bags and thus to losses of volume. Plate or bag hooks, which, due to their shape, distribute the load and reduce the risk of damage, should thus be used.


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RF Toxicity / Hazards to health

Respiration may cause life-threatening CO2 concentrations (TLV: 0.49 vol.%) or O2 shortages in the hold/container. Therefore, before anybody enters the hold, it must be ventilated and a gas measurement carried out.


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RF Shrinkage/Shortage

Bags which are torn or have been used several times may lead to slight losses in volume.


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RF Insect infestation / Diseases

Typical pests of oil-bearing seeds/fruits are, for example, merchant grain beetles, peanut weevils, sawtoothed grain beetles, flour beetles, grain mites, dried fruit moths and mites, which may cause depreciation and weight losses.


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